Combine paprika, sugar, 1/2 teaspoon black pepper, 1/4 teaspoon salt, and crushed red pepper in a small bowl. Rub paprika mixture evenly over pork. Place pork on grill rack coated with cooking spray. Grill 3 minutes on each side or until desired degree of doneness. Remove pork from grill.
Add zucchini to grill; grill 4 minutes on each side or until well marked. Cut zucchini into 1/2-inch pieces. Combine zucchini with remaining 1/4 teaspoon black pepper, remaining 1/4 teaspoon salt, oil, and mustard; toss to coat.
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The pork chop rub was great with a little heat. I used smoked paprika instead of regular and traded out 1 tsp of the paprika for 1 tsp of Chipotle seasoning to really give it that smoky flavor. It was awesome! The zucchini was a good compliment to the pork.
The flavor of the pork chops was very good, although I overcooked them by grilling them longer than the recipe suggested. I served them with corn on the cob. I grilled the zucchini another night. I'm not a huge fan of mustard, but the whole grain Dijon mustard I used was scrumptious with the grilled flavor of the zucchini.