1) Heat broiler, with rack in middle position. In a small bowl, combine oil, soy sauce, vinegar, garlic and red-pepper flakes. Divide mixture in half and stir jam into one half.
2) Place salmon on a broilerproof rimmed baking sheet lightly coated with cooking spray. Brush salmon with jam mixture and broil until fish is opaque throughout, about 10 minutes.
3) Meanwhile, set a steamer basket in a saucepan with 2 inches simmering water. Add broccoli, cover and steam until crisp-tender, 4 minutes. Toss broccoli with remaining soy sauce mixture, serve with salmon and rice.
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