Preheat oven to 400° . Line baking sheet with aluminum foil, then spray with nonstick cooking spray; set aside.
Brush chicken with Hellmann's® or Best Foods® Real Mayonnaise, then coat in bread crumbs. Arrange chicken on prepared baking sheet. Bake 15 minutes. Evenly top chicken with 4 slices ham and cheese. Bake an additional 5 minutes or until chicken is thoroughly cooked.
Meanwhile, prepare Knorr® Pasta Sides™ - Alfredo according to package directions, adding broccoli and remaining 2 slices ham, cut into 1/2-inch pieces, during last 3 minutes. Let stand about 2 minutes or until sauce is thickened. Serve with chicken.